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Journal of the Physical Society of Japan, 49(2), p.593 - 598, 1980/00
Times Cited Count:33 Percentile:85.63(Physics, Multidisciplinary)no abstracts in English
Journal of the Physical Society of Japan, 41(4), p.1437 - 1438, 1976/04
Times Cited Count:40no abstracts in English
Yoneda, Yasuhiro; Ohara, Koji*; Nagata, Hajime*
no journal, ,
KNbO has been a candidate for the end member of a non-Pb ferroelectric materials. We performed local structure analysis of KNbO bulk ceramics by high-energy synchrotron X-ray measurements. It has recently established that temperature-driven structural phase transitions in several perovskite ferroelectric materials (PbTiO, BaTiO, and NaNbO) believed to be purely displacive, have a significant order-disorder component. We performed the local structure analysis in a wide-temperature range to observe order-disorder feature of KNbO. The lowest temperature structure of KNbO is rhombohedral, and we found that the local rhombohedral distortion maintained in the high-temperature cubic phase.
Saito, Junichi; Takesue, Naohisa*; Kiba, Kazumasa*; Kudo, Junki*; Matsuo, Naoki*
no journal, ,
Saito, Junichi; Kiba, Kazumasa*; Kudo, Junki*; Matsuo, Naoki*; Takesue, Naohisa*
no journal, ,
Saito, Junichi; Kudo, Junki*; Kiba, Kazumasa*; Matsuo, Naoki*; Takesue, Naohisa*
no journal, ,
Saito, Junichi; Matsuo, Naoki*; Kiba, Kazumasa*; Kudo, Junki*; Takesue, Naohisa*
no journal, ,
Yoneda, Yasuhiro; Wada, Satoshi*
no journal, ,
BiFeO is a useful ferroelectric material, but it is not easy to reverse the polarization because the rhombohedral structure of the ferroelectric phase is greatly distorted, and attempts have been made to improve the dielectric properties by various additives. BaTiO and Bi(MgTi)O were selected as additives, and structural analysis was performed using synchrotron radiation. BiFeO has a rhombohedral structure and BaTiO has a tetragonal structure. Bi(MgTi)O has an antiferroelectric orthorhombic structure and is expected to behave as a buffer that binds BiFeO and BaTiO. The process of averaging the structure from micro to macro was clarified, and various changes were observed depending on the temperature. The flexibility of such a structure reduces the large distortion of BiFeO and enables polarization.